Competitive adsorption removal of sulphur compounds in gasoline using X zeolite
Abstract
The paper presents the results of sulphur removal from gasoline in a ternary system, i.e. benzene, 3 Methylthiophene (3-MT)/Benzothiophene (BT) and isooctane. These results indicate that the presence of aromatic compounds strongly reduces the efficiency of the removal of sulphur in gasoline. Moreover, it is found that the exchanged zeolite exhibits higher activity than the original and the type of sulphur containing compound plays an important role in the adsorption of sulphur in gasoline. A discussion on the obtained results is also presented.
References
Xiaoliang Ma, MichaelSprague, Chunshan Song. Deep desulfurization of gasoline by selective adsorption over nickel-based adsorbent for fuelcell applications. Industrial & Engineering Chemistry Reserch. 2005; 44(15): p. 5768 - 5775.
S.Mikhail, T.Zaki, L.Khalil. Desulfurization by an economically adsorption technique. Applied Catalysis A: General. 2001; 227(1 - 2): p. 265 - 278.
Scott G.McKinley, Robert J.Angelici. Deep desulfurization by selective adsorption of dibenzothiophenes on Ag+/SBA-15 and Ag+/SiO2. Chemical Communications. 2003; 20: p. 2620 - 2621.
Chunshan Song. An overview of new approaches to deep desulfurization for ultra-clean gasoline, diesel fuel and jet fuel. Catalysis Today. 2003; 86(1 - 4): p. 211 - 263.
S.Velu, S.Watanabe, X.Ma, C.Song. Development of selective adsorbents for removing sulfur from gasoline for fuel cell applications. American Chemical Society. 2003; 48(2): p. 56 - 57.
Ralph T.Yang, Arturo J.Hernández-Maldonado, Frances H.Yang. Desulfurization of transportation fuels with zeolites under ambient conditions. Science. 2003; 301 (5629): p. 79 - 81.
Nguyễn Anh Dũng, Cao Thu Hằng. Nghiên cứu loại lưu huỳnh trong xăng bằng phương pháp hấp phụ sử dụng zeolit X. Tạp chí Dầu khí. 2012; 11: trang 38 - 43.
J.Chansa. Removal of sulfur compounds from transportation fuels by adsorption. The Petroleum and Petrochemical College, Chulalongkorn University, Bangkok, Thailand. 2004.
S.Pringprayong. Adsorptive removal of sulfur compounds from transportation fuels using zeolitic adsorbents. The Petroleum and Petrochemical College Chulalongkorn University, Bangkok, Thailand. 2006.
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